New S/O-substituted ferrocenediyl ligands and their metal complexes.

نویسندگان

  • Robert C J Atkinson
  • Vernon C Gibson
  • Nicholas J Long
  • Lara J West
  • Andrew J P White
چکیده

New unsymmetrical S/O 1,1'-disubstituted ferrocenediyl ethers and hydroxides have been synthesised. The coordination chemistry of 1-(methylsulfanyl)-1'-(methoxy)ferrocene has been investigated with palladium(II) and platinum(II) precursors. With palladium(II), a bis-mu-chloro-bridged dimeric complex was obtained with the ligand bound solely through the thioether donor group. With platinum(II), a bis-ligand trans-sulfur ligated complex was obtained and structurally characterised.

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عنوان ژورنال:
  • Dalton transactions

دوره 29  شماره 

صفحات  -

تاریخ انتشار 2006